(R,R)-(+)-Vulcanolide
- this enantiomer develops a fragrance of a less
earthy character, with a woody side and the
strength of which is clearly inferior to the
(S,S)-enantiomer.
=
(+)-(6R,7R)-3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbaldehyde
Ref:
Charles
Fehr, Nathalie Chaptal-Gradoz, Syntheses of the
Enantiomers of Vulcanolide®, Volume 85,
Issue 2, Date: February 2002, Pages: 533-543;
Charles Fehr, Nathalie Chaptal-Gradoz,
José Galindo, Synthesis of
(-)-Vulcanolide by Enantioselective Protonation,
Chemistry - A European Journal, Volume 8, Issue
4, Date: February 15, 2002, Pages: 853-858;
Charles Fehr, Franqois Delay, Pierre-Main Blanc,
Nathalie Chaptal-Gradoz, United States Patent
No. 5,521,151, May 28, 1996; EP 664286 A1, July
26, 1995.
Vulcanolide
®
is a registered trademark of Firmenich
SA
|
|
(S,S)-(-)-Vulcanolide
- this enantiomer possesses the best developed
odor properties. Its musky, markedly earthy,
slightly amber character is particularly
powerful.
=
(-)-(6S,7S)-3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbaldehyde
Ref:
Charles
Fehr, Nathalie Chaptal-Gradoz, Syntheses of the
Enantiomers of Vulcanolide®, Volume 85,
Issue 2, Date: February 2002, Pages: 533-543;
Charles Fehr, Nathalie Chaptal-Gradoz,
José Galindo, Synthesis of
(-)-Vulcanolide by Enantioselective Protonation,
Chemistry - A European Journal, Volume 8, Issue
4, Date: February 15, 2002, Pages: 853-858;
Charles Fehr, Franqois Delay, Pierre-Main Blanc,
Nathalie Chaptal-Gradoz, United States Patent
No. 5,521,151, May 28, 1996; EP 664286 A1, July
26, 1995.
Vulcanolide
®
is a registered trademark of Firmenich
SA
|
|