(1R,6S)-(+)-tetrahydroionol
- diffusive amber odor with slightly floral,
orrisy and earthy note
(Yamamoto
et al.); also described as slightly floral and
orris-lke amber fragrance (Ohmoto et al. for a
95: 5 % ratio of trans/cis isomers)
Odor
Threshold = 400 ppb
=
(1'R,6'S)-(+)-
4-(2',2',6'-Trimethyl-cyclohexyl)-butan-2-ol
=
1-[(1'R,6'S)-2',2',6'-trimethylcyclohexyl]butan-3-ol
Note that the
C-3 position is epimeric, so this actually is a
mixture of (1'R,3S,6'S) & (1'R,3R,6'S)
isomers
Ref: Takeshi
Yamamoto,
Akemi Shimada, Tatsuya Ohmoto, Hiroyuki Matsuda,
Miharu Ogura and Tsuneyoshi
Kanisawa,
Flavour and Fragrance Journal, Volume 19, Issue
2, Date: March/April 2004, Pages: 121-133; T.
Yamamoto, H. Matsuda, T. Ohmoto, A. Shimada
& T. Sato, Proc. 12th Int. Congress of
Flavours, Fragrances & Essential oils,
Vienna, Austria, Oct. 4-8, 1992, pp.442-455;
Ohmoto, Tatsuya; Shimada, Akemi; Yamamoto,
Takeshi;
Propanol derivatives and perfumes containing the
same, United States Patent RE37,159 May 1, 2001
& United States Patent 5,250,512, Oct. 5,
1993, Assigned to Takasago International
Corp.
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(1S,6R)-(-)-tetrahydroionol
- faint vetiver-like woody odor
(Yamamoto
et al.); also described as a very faint woody
odor (Ohmoto et al. for a 95: 5 % ratio of
trans/cis isomers)
Odor
Threshold = 1000 ppb
=
(1'S,6'R)-(-)-
4-(2',2',6'-Trimethyl-cyclohexyl)-butan-2-ol
=
1-[(1'S,6'R)-2',2',6'-trimethylcyclohexyl]butan-3-ol
Note that the
C-3 position is epimeric, so this actually is a
mixture of (1'S,3R,6'R) & (1'S,3S,6'R)
isomers
Ref: Takeshi
Yamamoto,
Akemi Shimada, Tatsuya Ohmoto, Hiroyuki Matsuda,
Miharu Ogura and Tsuneyoshi
Kanisawa,
Flavour and Fragrance Journal, Volume 19, Issue
2, Date: March/April 2004, Pages: 121-133; T.
Yamamoto, H. Matsuda, T. Ohmoto, A. Shimada
& T. Sato, Proc. 12th Int. Congress of
Flavours, Fragrances & Essential oils,
Vienna, Austria, Oct. 4-8, 1992, pp.442-455;
Ohmoto, Tatsuya; Shimada, Akemi; Yamamoto,
Takeshi;
Propanol derivatives and perfumes containing the
same, United States Patent RE37,159 May 1, 2001
& United States Patent 5,250,512, Oct. 5,
1993, Assigned to Takasago International
Corp.
|
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