(+)-(2R,4aR,8aS)-Polywood®
- Odor properties: described as exhibiting a
rich, voluminous woody note with a powdery
ionone-like undertone.
Commercial
racemic Polywood is decribed as having a
tenacious and elegant woody note.
=
(+)-(2R,4aR,8aS)-5,5,8a-trimethyldecahydro-naphthalen-2-yl
acetate or (+)-(2R,4aR,8aS)-
perhydro-5,5,8a-trimethyl-2-naphthalenyl acetate
Ref:
Antoine
Gautier, Christian Vial, Cedric Morel, Marina
Lander, Ferdinand Naef, Preparation and Odor
Evaluation of Both Enantiomers of
3,4,4aa,5,6,7,8,8aß-Octahydro-5,5,8aß-trimethyl-2(1H)-naphthalenone
and
1,2a,3,4,4aa5,6,7,8,8aß-Decahydro-5,5,8aß-trimethyl-2ß-naphthalenyl
Acetate, Four Woody Odorants, Helv.Chim.Acta
1987, 70: 2039-2044; Paul A. Stadler, Albert
Eschenmoser, Erling Sundt, Oxygenated decalin
derivatives, United States Patent 3,989,739
(November 2, 1976); Paul A. Stadler, Albert
Eschenmoser, Erling Sundt, Perfume compositions
including oxygenated decalin derivatives, United
States Patent 3,928,246 (December 23, 1975); see
also Elisabetta Brenna, Claudio Fuganti and
Stefano Serra, Enantioselective perception of
chiral odorants, Tetrahedron: Asymmetry, 14,
142 (2003)
Polywood®
is a registered trademark of Firmenich
SA
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|
(-)-(2S,4aS,8aR)-Polywood®
- Odor properties: was found less rich than
(+)-(2R,4aR,8aS)-Polywood®, still woody,
dry, and amber-like.
=
(-)-((2S,4aS,8aR)-5,5,8a-trimethyldecahydro-naphthalen-2-yl
acetate or (-)-(2S,4aS,8aR)-
perhydro-5,5,8a-trimethyl-2-naphthalenyl acetate
Ref:
Antoine
Gautier, Christian Vial, Cedric Morel, Marina
Lander, Ferdinand Naef, Preparation and Odor
Evaluation of Both Enantiomers of
3,4,4aa,5,6,7,8,8aß-Octahydro-5,5,8aß-trimethyl-2(1H)-naphthalenone
and
1,2a,3,4,4aa5,6,7,8,8aß-Decahydro-5,5,8aß-trimethyl-2ß-naphthalenyl
Acetate, Four Woody Odorants, Helv.Chim.Acta
1987, 70: 2039-2044; Paul A. Stadler, Albert
Eschenmoser, Erling Sundt, Oxygenated decalin
derivatives, United States Patent 3,989,739
(November 2, 1976); Paul A. Stadler, Albert
Eschenmoser, Erling Sundt, Perfume compositions
including oxygenated decalin derivatives, United
States Patent 3,928,246 (December 23, 1975); see
also Elisabetta Brenna, Claudio Fuganti and
Stefano Serra, Enantioselective perception of
chiral odorants, Tetrahedron: Asymmetry, 14,
142 (2003)
Polywood®
is a registered trademark of Firmenich
SA
|
|