Chirality & Odour Perception
John C. Leffingwell, Ph.D.

The Ethyl 3-hydroxyhexanoates

You must have Java installed to view the molecular visualization on this page
Photo by permission of M. Roudintska - Art & Parfum

Ethyl (R)-(-)-3-hydroxyhexanoate - sweet, woody, fruity.

Odor threshold: 2.1 ng/L in air; 270 ppb in water (orthonasal); 63 ppb in water (retronasal)

The racemate has been described as citrus, pineapple, grape, fruity; also as fruity, fresh green, citrus, pineapple, grape

Ref: Andrea Buettner and Peter Schieberle, Evaluation of Key Aroma Compounds in Hand-Squeezed Grapefruit Juice (Citrus paradisi Macfayden) by Quantitation and Flavor Reconstitution Experiments, J. Agric. Food Chem. 2001, 49, 1358-1363; see for example ethyl 3-hydroxyhexanoate (Good Scents Co.)

Ethyl (S)-(+)-3-hydroxyhexanoate - weak fruity and aldehyde-like.

Odor threshold: 264.5 ng/L in air

Ref: Andrea Buettner and Peter Schieberle, Evaluation of Key Aroma Compounds in Hand-Squeezed Grapefruit Juice (Citrus paradisi Macfayden) by Quantitation and Flavor Reconstitution Experiments, J. Agric. Food Chem. 2001, 49, 1358-1363

Cyclic Terpenoid Odorants

Bicyclic Terpenoid Odorants

Acyclic Terpenoid Odorants

Ionones, Irones, Damascones & Structurally Related Odorants

Acyclics (Alcohols, Esters, Acids, Aldehydes)

Lactones

Sesquiterpenoid Related Odorants

Steroid Urine Type Odorants

Sandalwood Type Odorants

Musk Odorants

Miscellaneous

HOME

Copyright 2001-2002 - Leffingwell & Associates