(-)-(6R)-3,4-Didehydro-gamma-ionone
- weaker than (+)-(S)-isomer, fruity-floral,
slightly woody
Odor
threshold = 0.25 ng/L in air
=
(-)-(3E)-4-[(1R)-6,6-dimethyl-2-methylenecyclohex-3-en-1-yl]but-3-en-2-one
Ref: Stefano
Serra, Claudio Fuganti, and Elisabetta Brenna,
Synthesis, Olfactory Evaluation, and
Determination of the Absolute Configuration of
the 3,4-Didehydroionone Stereoisomers, Helvetica
Chimica Acta, Vol. 89 (2006),
1110-1122.
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(+)-(6S)-3,4-Didehydro-gamma-ionone
- stronger than (-)-(R)-isomer on blotter,
floral-woody, cetonal-like, slightly fruity,
damasconic, sweet
Odor
threshold = 0.080 ng/L in air
=
(+)-(3E)-4-[(1S)-6,6-dimethyl-2-methylenecyclohex-3-en-1-yl]but-3-en-2-one
Ref: Stefano
Serra, Claudio Fuganti, and Elisabetta Brenna,
Synthesis, Olfactory Evaluation, and
Determination of the Absolute Configuration of
the 3,4-Didehydroionone Stereoisomers, Helvetica
Chimica Acta, Vol. 89 (2006),
1110-1122.
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