(6S)-(+)-8,9-dehydrotheaspirone
- Fruity-floral aroma (Kataoka, et. al.);
floral, woody-ambery, powdery, reminiscent of
Cetonal with natural fruity, orris-like facets
(Serra, et. al.).
Odor
threshold = 100 ppb (Kataoka, et.
al.)
Odor
threshold (5 panellists) = 9.8 ng/L air (Serra,
et. al.).
=
(+)-(5S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]deca-2,6-dien-8-one
Ref: Hitomi
Kataoka, Hideki Nakamoto, Taro Kitauro, Masakazu
Ishihara, Perfume Quality Improver, Perfume
Composition, Cosmetic or Food, Japanese Patent
Publication No. 2002069480 (March 8, 2002);
Stefano Serra, Assem Barakat and Claudio
Fuganti, Chemoenzymatic resolution of cis- and
trans-3,6-dihydroxy-a-ionone. Synthesis of the
enantiomeric forms of dehydrovomifoliol and
8,9-dehydrotheaspirone, Tetrahedron: Asymmetry
18 (2007) 25732580.
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(6R)-(-)-8,9-dehydrotheaspirone
- Woody aroma (Kataoka, et. al.); woody, dry,
cedarwood odor with a green, earthy, tobacco and
olibanum inflection and floral-fruity nuances
(Serra, et. al.).
Odor
threshold = 500 ppb (Kataoka, et.
al.)
Odor
threshold (5 panellists) = 13.7 ng/L air (Serra,
et. al.).
=
(-)-(5R)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]deca-2,6-dien-8-one
Ref: Hitomi
Kataoka, Hideki Nakamoto, Taro Kitauro, Masakazu
Ishihara, Perfume Quality Improver, Perfume
Composition, Cosmetic or Food, Japanese Patent
Publication No. 2002069479 (March 8, 2002);
Stefano Serra, Assem Barakat and Claudio
Fuganti, Chemoenzymatic resolution of cis- and
trans-3,6-dihydroxy-a-ionone. Synthesis of the
enantiomeric forms of dehydrovomifoliol and
8,9-dehydrotheaspirone, Tetrahedron: Asymmetry
18 (2007) 25732580.
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