c
-4-acetylthio-2-octanone.gif)
(4R)-4-acetylthio-2-octanone
- more unpleasant (catty, sulfury) descriptions
for the (R)-enantiomer (by GC-O)
Odor
Threshold = 24 ng/L air
=
S-[(2R)-4-oxooctan-2-yl]
ethanethioate
Ref: M.
Wakabayashi, H. Wakabayashi, S. Nörenberg,
B. Reichardt, K. Kubota, K.-H. Engel, Analytical
and Sensory Characterization of Chiral
4-Mercapto-2-alkanones,
4-Acetylthio-2-alkanones, and the Corresponding
Alcohols, ACS Symposium Series, Vol. 1098,
Recent Advances in the Analysis of Food and
Flavors, Chapter 3, pp 2739,
2012
|
c
|
(4S)-4-acetylthio-2-octanone
- more fruity-pleasant (grapefruit,
blackcurrant) notes for the (S)-enantiomer (by
GC-O)
Odor
Threshold = 57 ng/L air
=
S-[(2S)-4-oxooctan-2-yl]
ethanethioate
Ref: M.
Wakabayashi, H. Wakabayashi, S. Nörenberg,
B. Reichardt, K. Kubota, K.-H. Engel, Analytical
and Sensory Characterization of Chiral
4-Mercapto-2-alkanones,
4-Acetylthio-2-alkanones, and the Corresponding
Alcohols, ACS Symposium Series, Vol. 1098,
Recent Advances in the Analysis of Food and
Flavors, Chapter 3, pp 2739,
2012
|
|